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recycling silver and palladium

     

(1) Mercury and Palladium Add nitric acid to the alloy and stir, heat the solution to approximately 50°C, allowing mercury and palladium to dissolve. Filter the solution to obtain filtrate and residue. The residue contains gold and platinum, which are then fed into the precious metal refining process.

(2) Silver Deposition Add hydrochloric acid to the solution in the reaction container to form silver chloride precipitate. Filter the solution to obtain silver chloride powder and palladium-containing solution. Process the silver chloride for precious metal recovery, while the palladium-containing solution is processed for palladium recovery.

(3) Replacement Add silver chloride to the reaction container and dissolve it in water. Add iron powder for replacement. Filter the solution. The residue is coarse silver powder.

(4) Palladium Oxidation Transfer the palladium-containing solution into a reactor, add 10% sodium chlorate solution for oxidation. After 1-2 hours of oxidation, add ammonium chloride to precipitate palladium. Filter after the reaction is complete and transfer the filtrate to the replacement unit.

Palladium Refining Process: 

1) Palladium Refining 

① Complex Dissolution Transfer ammonium palladium chloride into the refining process. Add an appropriate amount of water for solvation. Add ammonia for complexation, heating the solution to 80°C during this step. Filter after dissolution.

② Acidification and Precipitation Transfer the complex solution to a reactor, slowly add hydrochloric acid for acidification. Filter after reaction completion, transferring the filtrate to the replacement unit.

③ Reduction by Ammonia After two complexations and acidifications, perform a third complexation. Add prepared ammonium water solution (80%) in the ratio of 1 kg palladium to 1 Lammonium water. Slowly add the yellow powder solution, heat to boiling, stir thoroughly until the solution is completely reduced. Filter and wash the residue. The filtrate is sent to the replacement unit, while the residue becomes palladium sponge.

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